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Elements as Direct Feedstocks for Organic Synthesis: Fe/I2/O2 for Diamination of 2‑Cyclohexenones with 2‑Aminopyrimidine and 2‑Aminopyridines

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Figshare2016-02-12 更新2026-04-29 收录
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Elements as feedstocks for organic synthesis, the trio of metallic iron, molecular iodine, and dioxygen, were found to be an excellent tool for oxidative regioselective diamination of conjugated enones with 2-aminopyrimidine (a guanidine surrogate) and 2-aminopyridines leading to unaromatized coupled products in moderate to good yields.

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2016-02-12
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