C−C Bond-Forming Reductive Elimination from a Zirconium(IV) Redox-Active Ligand Complex
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https://figshare.com/articles/dataset/C_C_Bond_Forming_Reductive_Elimination_from_a_Zirconium_IV_Redox_Active_Ligand_Complex/3072952
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资源简介:
Carbon−carbon bond-forming reductive elimination of biphenyl is observed upon two-electron oxidation of the [ZrIVPh2(ap)2]2- dianion. Crossover experiments confirm that the C−C bond-forming step occurs at a single zirconium metal center. The reactivity is enabled by the participation of a redox-active amidophenolate ligand set.
创建时间:
2016-03-01



