Reductive N−N Bond Cleavage of Diphenylhydrazine and Azobenzene Induced by Coordinatively Unsaturated Cp*Fe{N(SiMe<sub>3</sub>)<sub>2</sub>}
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The coordinatively unsaturated iron(II) amido complex Cp*Fe{N(SiMe3)2} (1) serves as an efficient precursor for the cleavage of the N−N bond of diphenylhydrazine. The NN bond of azobenzene was also found to be activated by 1 in the presence of pinacolborane.
创建时间:
2016-03-01



