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The Structure and Synthesis of Plutonium(III) Chlorides from Aqueous Solution

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https://figshare.com/articles/dataset/The_Structure_and_Synthesis_of_Plutonium_III_Chlorides_from_Aqueous_Solution/3053269
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资源简介:
The preparation and structure of three trivalent plutonium chloride compounds from aqueous solution is reported. Two of the three are plutonium tetraaquatetrachloro complexes exhibiting a cis and a trans arrangement of Cl about the Pu. The identification of the coordination number of 4 with respect to Cl and the isomerism are both unprecedented in actinide solution chemistry. The third complex is a hexaaquadichloro complex of Pu(III), predicted by available thermodynamic data.
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2006-10-16
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