A Tridentate-Dithiolate Ruthenium Alkylidene Complex: An Olefin Metathesis Catalyst Activated by BCl<sub>3</sub>
收藏NIAID Data Ecosystem2026-03-07 收录
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资源简介：
The Ru dithiolate alkylidene species (SIMes)Ru(CHPh)(O(CH2CH2S)2) (1) reacts with 1 and 2 equiv of BCl3 to give (SIMes)RuCl(CHPh)(Cl2B(SCH2CH2)2O) (2) and [(SIMes)Ru(CHPh)(Cl2B(SCH2CH2)2O)][BCl4] (3), respectively. Compounds 1 and 2 are inactive in ROMP, RCM, and CM reactions, whereas 3 is an active catalyst for these metatheses.
创建时间：
2013-09-09
