Activation of C–F and Ni–C Bonds of [P,S]-Ligated Nickel Perfluorometallacycles
收藏NIAID Data Ecosystem2026-03-08 收录
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The first example of a [P,S]-ligated metal perfluorocyclopentane is reported. The new metallacycle undergoes Cα–F activation in the presence of a Lewis acid, followed by chemoselective ligand migration, affording a fused metallabicyclic product. Reactivity of this product includes an unprecedented nucleophile-induced ring-opening reaction, involving loss of a β-fluoride. Additionally, hydrolysis of the metallabicyclic product affords a single isomer of hexafluoro-1-butene.
创建时间：
2016-02-18
