Isomers of a Dibismuthane, R<sub>2</sub>Bi−BiR<sub>2</sub> [R = 2,6-(Me<sub>2</sub>NCH<sub>2</sub>)<sub>2</sub>C<sub>6</sub>H<sub>3</sub>], and Unusual Reactions with Oxygen: Formation of [R<sub>2</sub>Bi]<sub>2</sub>(O<sub>2</sub>) and R‘R‘ ‘Bi [R‘ = 2-(Me<sub>2</sub>NCH<sub>2</sub>)-6-{Me<sub>2</sub>N(O)CH<sub>2</sub>}C<sub>6</sub>H<sub>3</sub>; R‘ ‘ = 2-(Me<sub>2</sub>NCH<sub>2</sub>)-6-{O(O)C}C<sub>6</sub>H<sub>3</sub>]
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数据链接：
https://figshare.com/articles/dataset/Isomers_of_a_Dibismuthane_R_sub_2_sub_Bi_BiR_sub_2_sub_R_2_6_Me_sub_2_sub_NCH_sub_2_sub_sub_2_sub_C_sub_6_sub_H_sub_3_sub_and_Unusual_Reactions_with_Oxygen_Formation_of_R_sub_2_sub_Bi_sub_2_sub_O_sub_2_sub_and_R_R__Bi_R_2_Me_sub_2_sub_NCH_sub_2_sub_6_Me_s/3234997数据链接链接失效反馈
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资源简介：
R2Bi−BiR2 [1; R = 2,6-(Me2NCH2)2C6H3], a dibismuthane that exists in different forms in the crystalline state, reacts in air with the formation of the peroxide [R2Bi]2(O2) (2) and partial oxidation of the pendant (dimethylamino)methyl groups, yielding the mononuclear bismuth complex R‘R‘ ‘Bi (3) [R‘ = 2-(Me2NCH2)-6-{Me2N(O)CH2}C6H3; R‘ ‘ = 2-(Me2NCH2)-6-{O(O)C}C6H3].
创建时间：
2016-05-05
