Highly Selective Hydrocyanation of Butadiene toward 3-Pentenenitrile
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https://figshare.com/articles/dataset/Highly_Selective_Hydrocyanation_of_Butadiene_toward_3_Pentenenitrile/2979415
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资源简介:
A triptycene-based diphosphine ligand was synthesized in good yield following a new route. The corresponding Pt(II)- and Ni(0)-complexes were characterized. In butadiene hydrocyanation the tript-PPh2Ni(cod) catalyst leads to exceptionally high selectivities for the linear product 3-pentenenitrile, combining high activity for both hydrocyanation and isomerization. This one-step procedure could be the key toward process intensification.
创建时间:
2016-02-28



