Formation of a σ‑alkane Complex and a Molecular Rearrangement in the Solid-State: [Rh(Cyp2PCH2CH2PCyp2)(η2:η2‑C7H12)][BArF4]
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https://figshare.com/articles/dataset/Formation_of_a_alkane_Complex_and_a_Molecular_Rearrangement_in_the_Solid-State_Rh_Cyp_sub_2_sub_PCH_sub_2_sub_CH_sub_2_sub_PCyp_sub_2_sub_sup_2_sup_sup_2_sup_C_sub_7_sub_H_sub_12_sub_BAr_sup_F_sup_sub_4_sub_/3854373
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Addition of H2 to the precursor [Rh(Cyp2PCH2CH2PCyp2)(η2:η2-C7H8)][BArF4] gives the σ-alkane complex [Rh(Cyp2PCH2CH2PCyp2)(η2:η2-C7H12)][BArF4] by a single-crystal to single-crystal reaction, as characterized by X-ray crystallography, SSNMR spectroscopy, and periodic DFT. An unexpected rearrangement of the {Rh(L2)}+ fragment is revealed.
创建时间：
2016-10-27
