Triazacyclohexane (tach) Complexes of High-Valent Rhenium: Syntheses of [(R<sub>3</sub>tach)ReO<sub>3</sub>]<sup>+</sup> (R = −CH<sub>3</sub>, −CH<sub>2</sub>C<sub>6</sub>H<sub>5</sub>) and Its Substitution Reactions
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N-Alkylated derivatives of 1,3,5-triazacyclohexane (tach) are versatile, facially coordinating ligands. We present the syntheses and full characterization of two new complexes of the [(R3tach)ReO3]+ type. In these complexes, the tach ligand is readily substituted by bi- and tridentate ligands; hence, they can be considered as sources of the [ReO3]+ motif for ReVII complexes.
创建时间：
2016-02-25
