Bis(imino)phosphanes: Synthesis and Coordination Chemistry
收藏NIAID Data Ecosystem2026-03-09 收录
下载链接：
https://figshare.com/articles/dataset/Bis_imino_phosphanes_Synthesis_and_Coordination_Chemistry/3051712
下载链接
链接失效反馈官方服务：
资源简介：
Bis(imino)phosphanes can be synthesized
efficiently from iminophosphanes
and nitrilium triflates, allowing for nonsymmetric substitution at
the imine groups. Symmetrically substituted derivatives can even be
obtained in a one-pot procedure from primary phosphanes. These potential
N,N-bidentate ligands are sensitive toward Cu(II), Zn(II), and rhodium(I)
sources, resulting in loss of an imine group. For [RhCl(COD)]2 this led to an N,P- and P-chelating bimetallic complex. Bis(imino)phosphanes
with C-Me substituents rearrange in situ to unique
1,3,5-phosphadiazapentadienes for which a P-coordinated gold(I) complex
is reported. The bis(imino)phosphanes are readily oxidized to stable
bis(imino)phosphane oxides with aqueous H2O2.
创建时间：
2016-03-08
