Isolable Pincer-type Dianionic Dialane(6)
收藏NIAID Data Ecosystem2026-03-13 收录
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https://figshare.com/articles/dataset/Isolable_Pincer-type_Dianionic_Dialane_6_/19369122
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资源简介：
Although
pincer-type main group complexes have attracted considerable
attention owing to their unique structures and intriguing reactivity,
the isolation of pincer-type dianionic dialane(6) is still elusive.
Herein we report the first synthesis of the dianionic dialane(6) species 4 bearing novel redox-active trinitrogen pincer ligands by
reduction of the aluminum diiodide precursor 3 with excess
potassium graphite. The structure of 4 has been investigated
by spectroscopic analysis, X-ray crystallography, and density functional
theory calculations, which reveal that 4 possesses an
Al–Al single covalent bond and twisted trianionic pincer ligands.
创建时间：
2022-03-16
