Reaction of Cp*Ir(CO)<sub>2</sub> with Activated Perfluoroaromatic Compounds: Formation of Metallocarboxylic Acids via Aromatic Nucleophilic Substitution
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The reaction of Cp*Ir(CO)2 with activated perfluoroaromatic compounds such as pentafluoropyridine and -benzonitrile afforded the metallocarboxylic acids Cp*Ir(COOH)(L)(CO), L = C5F4N or C6F4CN, respectively. The reaction probably proceeds via aromatic nucleophilic substitution followed by nucleophilic attack by water at one of the carbonyl ligands.
创建时间：
2016-02-27
