Oxidation of Ni-ECp* Complexes: Stable Open-Shell NiI Cations [Ni(ECp*)n(PPh3)4–n]+ (n = 2, 4; E = Al, Ga)
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Uncommon NiI cationic complexes were synthesized by treating [Ni(ECp*)2(PPh3)2] (E = Al, Ga; Cp* = pentamethylcyclopentadienyl) with 1 equiv of [FeCp2][BAr4F]. All compounds have been prepared readily in high yield. The paramagnetic compounds were characterized by single-crystal X-ray crystallography, mass spectrometry, elemental analysis, magnetic susceptibility, and electron paramagnetic resonance spectroscopy.
创建时间:
2016-02-12



