Photochemical Rearrangement of N-Mesyloxylactams: Stereospecific Formation of N-Heterocycles
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https://figshare.com/articles/dataset/Photochemical_Rearrangement_of_i_N_i_Mesyloxylactams_Stereospecific_Formation_of_i_N_i_Heterocycles/2699914
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N-Mesyloxylactams undergo an efficient ring-contraction to N-heterocycles of various ring sizes. Yields increase with the degree of substitution α to the carbonyl. The stereochemical information of a chiral migrating carbon is conserved making this reaction a synthetically useful complement to the well-known Hofmann, Curtius, Lossen, and Schmidt rearrangements.
创建时间：
2016-02-24
