Zirconium-Catalyzed Heterodehydrocoupling of Primary Phosphines with Silanes and Germanes
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https://figshare.com/articles/dataset/Zirconium_Catalyzed_Heterodehydrocoupling_of_Primary_Phosphines_with_Silanes_and_Germanes/2990371
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资源简介：
Triamidoamine-supported zirconium complexes catalyze the heterodehydrocoupling of primary phosphines with silane and germanes. In this catalysis, P−Si or P−Ge products are observed
exclusively with no competitive P−P bond formation. Phosphido
complexes (N3N)ZrPHR (N3N = N(CH2CH2NSiMe3)33-, R = Ph,
2; Cy, 3) were observed to be the catalyst resting state, and
complex 2 was structurally characterized.
创建时间：
2016-06-03
