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Synthesis, Structure, and Properties of a Stable 1,2-Dibromodialumane(4) Bearing a Bulky Aryl Substituent

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https://figshare.com/articles/dataset/Synthesis_Structure_and_Properties_of_a_Stable_1_2_Dibromodialumane_4_Bearing_a_Bulky_Aryl_Substituent/2523169
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资源简介:
The stable 1,2-dibromodialumane(4) Bbp­(Br)­Al–Al­(Br)­Bbp (1; Bbp = 2,6-bis­[bis­(trimethylsilyl)­methyl]­phenyl) was synthesized by the reduction of the corresponding dibromoalumane etherate BbpAlBr2·OEt2 (2). The structure and properties of 1 have been elucidated on the basis of the analyses of spectroscopic and crystallographic data and are supported by DFT calculations.
创建时间:
2016-02-20
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