Regioselective Decarboxylative Direct C–H Arylation of Boron Dipyrromethenes (BODIPYs) at 2,6-Positions: A Facile Access to a Diversity-Oriented BODIPY Library
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https://figshare.com/articles/dataset/Regioselective_Decarboxylative_Direct_C_H_Arylation_of_Boron_Dipyrromethenes_BODIPYs_at_2_6_Positions_A_Facile_Access_to_a_Diversity_Oriented_BODIPY_Library/2228305
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资源简介：
A palladium-catalyzed regioselective
decarboxylative direct C–H
arylation of boron dipyrromethenes (BODIPYs) at the 2,6-positions
has been developed as a late-stage approach to rapidly assemble a
diversity-oriented BODIPY library. With the complement of this protocol,
the direct C–H arylation of BODIPYs becomes regiocontrollable
at α- and β-positions. A new type of indole-fused BODIPY
exhibiting bright red/NIR fluorescence with a large molar extinction
coefficient (145 500 M–1 cm–1) and a high quantum yield (71%) has been synthesized for the first
time.
创建时间：
2016-02-16
