Synthesis and spectral properties for 3, 7-dithiatricyclo[6.4.0.0²˒¹⁰.0 ⁹˒¹¹]dodecane (norDTCO) and 3-λ⁴, 7-dithiatricyclo[6.4.0.0²˒¹⁰.0 ⁹˒¹¹]dodecan-3-one (norDTCO sulfoxide)
收藏DataCite Commons2026-01-29 更新2026-04-25 收录
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https://datadryad.org/dataset/doi:10.5061/dryad.4b8gthtsx
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资源简介：
The synthesis, tabulated infrared and 1H NMR spectra of the title
compounds: 3, 7-dithiatricyclo[6.4.0.02,10.09,11]dodecane
(norDTCO) and 3λ4,
7-dithiatricyclo[6.4.0.02,10.09,11]dodecan-3-one (norDTCO sulfoxide) are
presented. The compound norDTCO is a substituted 1,5-dithiocane which can
oxidize chemically or electrochemically by two-electrons to a dication
with a transannular S-S sigma-bond. Its derivative, norDTCO sulfoxide, is
the ultimate product after a two-electron oxidation and the addition of
water.
提供机构：
Dryad
创建时间：
2026-01-05
