Photochemical cyclopropanation in aqueous micellar media – experimental and theoretical studies
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The synthesis of cyclopropanes constitutes one of the fundamental reactions in the repertoire of carbene-derived processes and can be accomplished in water-based systems. In micellar systems, the photochemical reaction of diazo compounds with styrenes in the absence of a metal catalyst gave products in moderate to excellent yields and with good diastereoselectivity.
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2024-07-16



