Star-Shaped Pyrrole-Fused Tetrathiafulvalene Oligomers: Synthesis and Redox, Self-Assembling, and Conductive Properties
收藏NIAID Data Ecosystem2026-03-07 收录
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A series of star-shaped pyrrole-fused tetrathiafulvalene (TTF) oligomers 1–3 was synthesized via an SNAr reaction of fluorinated benzenes with the pyrrolyl sodium salts. Electrochemical and chemical oxidations of 1–3 revealed that a radical cation moiety on each TTF unit was successfully accumulated in all oligomers. Self-assembled structures of neutral and oxidized species were characterized by SEM and XRD, and their conductive properties of the iodine-doped 1–3 as well as an intermolecular mixed-valence ion radical salt were investigated.
创建时间：
2016-02-23
