Synthesis, Structure, and Antibacterial Activity of a Thallium(III)-Containing Polyoxometalate, [Tl<sub>2</sub>{<i>B</i>‑β-SiW<sub>8</sub>O<sub>30</sub>(OH)}<sub>2</sub>]<sup>12–</sup>
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We have synthesized and structurally characterized the first discrete thallium-containing polyoxometalate, [Tl2{B-β-SiW8O30(OH)}2]12– (1). Polyanion 1 was characterized in the solid-state and shown to be solution-stable by 203/205Tl NMR, electrospray ionization mass spectrometry, and electrochemical studies. The antibacterial activity of 1 was also investigated.
创建时间:
2016-10-11



