Asymmetric Synthesis of β-Hydroxy Sulfides Controlled by Remote Sulfoxides
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https://figshare.com/articles/dataset/Asymmetric_Synthesis_of_Hydroxy_Sulfides_Controlled_by_Remote_Sulfoxides/3029575
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资源简介：
Reactions of (S)-α-(methylthio)-2-(p-tolylsulfinyl)benzyl carbanion with different carbonyl compounds proceeds with
complete control of the configuration at the benzylic position.
Aldehydes yield easily separable mixtures of β-hydroxy
sulfides, epimers at the hydroxylic carbon, where the
stereoselectivity depends on steric factors (from 20% to
>98% de).
创建时间：
2016-02-29
