Asymmetric Synthesis of β-Hydroxy Sulfides Controlled by Remote Sulfoxides
收藏NIAID Data Ecosystem2026-03-06 收录
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资源简介：
Reactions of (S)-α-(methylthio)-2-(p-tolylsulfinyl)benzyl carbanion with different carbonyl compounds proceeds with complete control of the configuration at the benzylic position. Aldehydes yield easily separable mixtures of β-hydroxy sulfides, epimers at the hydroxylic carbon, where the stereoselectivity depends on steric factors (from 20% to >98% de).
创建时间：
2016-02-29
