Novel Expansion/Shrinkage Modulation of 2D Layered MOF Triggered by Clathrate Formation with CO<sub>2</sub> Molecules
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Crystal-to-crystal transformation from a 3D interpenetrated-type MOF {[Cu(BF4)2(bpy)(H2O)2] (bpy)} (1) to a 2D square-grid-type [Cu(BF4)2(bpy)2] (2) (bpy = 4,4‘-bipyridine) was observed. It was derived from dehydration and confirmed by in situ FT-IR, TG, and elemental analysis. Moreover, we elucidate the novel expansion/shrinkage dynamic modulation of 2 triggered by clathrate formation with gas molecules.
创建时间：
2006-11-08
