Cooperative Catalysis: Large Rate Enhancements with Bimetallic Rhodium Complexes
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https://figshare.com/articles/dataset/Cooperative_Catalysis_Large_Rate_Enhancements_with_Bimetallic_Rhodium_Complexes/2379343
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资源简介：
A large
increase in reaction rate was observed for the catalyzed mono- and
dihydroalkoxylation of alkynes when structurally constrained bimetallic
Rh(I) catalysts with imidazolyl-imine ligands were compared to their
monometallic analogues. The “cooperative” enhancement
was vastly improved by restricting the conformational freedom of the
bimetallic structure and minimizing the intermetallic Rh···Rh
distance.
创建时间：
2013-09-09
