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Three-Stage Binary Switching of Azoaromatic Polybase

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Figshare2016-02-20 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Three_Stage_Binary_Switching_of_Azoaromatic_Polybase/2458663
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An OFF–ON–OFF-type three-stage binary switching was realized with an azoaniline-based polybase 1. The optical properties of 1 and [1·2H]2+ are essentially indistinguishable to the naked eye but distinctively different from those of [1·H]+ to produce an unusual bell-shaped response as a function of protonation state; the underlying molecular mechanism was unraveled by a combination of experimental and DFT computational studies.
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2016-02-20
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