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Site-Selective Carbene-Induced C–H Functionalization Catalyzed by Dirhodium Tetrakis(triarylcyclopropanecarboxylate) Complexes

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NIAID Data Ecosystem2026-03-10 收录
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Three types of dirhodium tetrakis­(tri­aryl­cy­clo­pro­pane­car­boxy­late) complexes were generated and shown to adopt disparate high-symmetry structures. These catalysts were evaluated in the intermolecular C–H functionalization of an array of terminally substituted n-alkanes and displayed various site-selectivity as a function of catalyst and substrate structure, which could be correlated through quantitative relationships.

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2017-12-20
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