A Metal-Directed Self-Assembled Electroactive Cage with Bis(pyrrolo)tetrathiafulvalene (BPTTF) Side Walls
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https://figshare.com/articles/dataset/A_Metal_Directed_Self_Assembled_Electroactive_Cage_with_Bis_pyrrolo_tetrathiafulvalene_BPTTF_Side_Walls/2502325
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A straightforward synthesis of a bis(pyrrolo)tetrathiafulvalene (BPTTF)-based tetratopic ligand bearing four pyridyl units is described. The first example of a TTF-based self-assembled cage has been produced from this redox-active ligand through metal-directed synthesis with a cis-coordinated square-planar Pt(II) complex. The resulting cage corresponds to a trigonal-prismatic structure, as shown by X-ray crystallography. A UV–vis titration indicated that the electron-rich cavity can be used to incorporate one molecule of tetrafluorotetracyano-p-quinodimethane (TCNQF4).
创建时间：
2016-02-20
