N‑Heterocyclic Carbene-Catalyzed Formal Intramolecular [3 + 2] Annulations of Cyclohexadienone-Tethered Ynals
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https://figshare.com/articles/dataset/N_Heterocyclic_Carbene-Catalyzed_Formal_Intramolecular_3_2_Annulations_of_Cyclohexadienone-Tethered_Ynals/25651572
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资源简介：
A formal [3 + 2] annulation of cyclohexadienone-tethered
ynals
is enabled by an N-heterocyclic carbene (NHC) catalyst, affording
a tricyclo[6.2.1.04,11]undecane framework. This study represents
the first demonstration of using CC double bonds as the reaction
partner in the NHC-catalyzed annulation of ynals. This strategy is
characterized by mild reaction conditions and 100% atom economy as
well as high catalytic performance and efficiency.
创建时间：
2024-04-19
