Ligand-Directed Assembly of Polyoxovanadate-Based Metal–Organic Polyhedra
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https://figshare.com/articles/dataset/Ligand-Directed_Assembly_of_Polyoxovanadate-Based_Metal_Organic_Polyhedra/3574398
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资源简介：
Three new polyoxovanadate-based
metal–organic polyhedra (VMOPs) have been successfully synthesized
and structurally characterized. Single crystals of three VMOPs were
obtained by reaction of VCl3 and different carboxylate
ligands (2,5-H2TDA = thiophene-2,5-dicarboxylic acid for VMOP-4, m-H2BDC =
1,3-benzenedicarboxylic acid for VMOP-5,
2,6-H2NDC = 2,6-naphthalenedicarboxylic aid for VMOP-6) under solvothermal conditions. Though all of the
three hybrids feature the same {VVV4IV} units, their structures exhibit differences changing from truncated
triangular prism to truncated quadrangular prism to octahedron, mainly
depending on the nature of carboxylate ligands. Furthermore, the magnetic
investigations reveal that VMOP-4–6 show similar ferromagnetic behaviors.
创建时间：
2016-08-31
