A Structurally Rigid Bis(amido) Ligand Framework in Low-Coordinate Ni(I), Ni(II), and Ni(III) Analogues Provides Access to a Ni(III) Methyl Complex via Oxidative Addition
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https://figshare.com/articles/dataset/A_Structurally_Rigid_Bis_amido_Ligand_Framework_in_Low_Coordinate_Ni_I_Ni_II_and_Ni_III_Analogues_Provides_Access_to_a_Ni_III_Methyl_Complex_via_Oxidative_Addition/2365981
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资源简介:
A structurally
persistent bis-amido ligand framework capable of
supporting nickel compounds in three different oxidation states has
been identified. A highly unusual, isolable Ni(III) alkyl species
has been prepared and characterized via a rare example of a two-electron
oxidative addition of MeI to Ni(I).
创建时间:
2016-02-18



