Synthesis and Functionalization of 3-Alkylidene-1,2-diazetidines Using Transition Metal Catalysis
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https://figshare.com/articles/dataset/Synthesis_and_Functionalization_of_3_Alkylidene_1_2_diazetidines_Using_Transition_Metal_Catalysis/2673067
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资源简介：
An efficient two-step synthesis of a wide range of 3-methylene-1,2-diazetidines has been developed through application of a Cu(I)-catalyzed 4-exo ring closure. The double bond of this new class of strained heterocycle can be functionalized in a stereocontrolled manner by using palladium-catalyzed Heck reactions. Moreover, chemoselective reduction of 3-alkylidene-1,2-diazetidines gives access to saturated 1,2-diazetidines and vicinal diamines.
创建时间：
2011-04-01
