Three 2D/2D → 2D or 3D Coordination Polymers: Parallel Stacked, Interpenetration, and Polycatenated
收藏NIAID Data Ecosystem2026-03-08 收录
下载链接：
https://figshare.com/articles/dataset/Three_2D_2D_2D_or_3D_Coordination_Polymers_Parallel_Stacked_Interpenetration_and_Polycatenated/2358496
下载链接
链接失效反馈官方服务：
资源简介：
Three
fascinating coordination polymers, {[Zn2(TPPBDA)(HCO2–)4]·2H2O}n (1), {[Zn(TPPBDA)1/2(4,4′-sdb)]·2H2O }n (2), and {[Zn(TPPBDA)1/2(oba)·2DMF·2H2O]}n (3), have been
successfully synthesized and characterized by the self-assembly of
the TPPDBA ligand as well as Zn2+ metal salts, or in the
presence of carboxylate ligands (TPPDBA = N,N,N′,N′-tetrakis(4-(4-pyridine)-phenyl)
biphenyl-4,4′-diamine), 4,4′-H2sdb = 4,4′-sulfonyldibenzoate,
4,4′-H2oba = 4,4′-oxybis(benzoate), DMF = N,N-dimethylformamide). In complex 1, the 2D ABAB parallel stacked network in which left- and
right-handed helical chains coexist and array alternately (2Dchiral/2Dchiral → 2Dachiral) makes 1 give rise to a new interesting 2D interwoven network. Complex 2 exhibits a 2D + 2D → 2D parallel interpenetrated
network. For compound 3, the polycatenation among the
2D layer further extends the 2D net into a 3D framework.
创建时间：
2013-11-06
