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Selective Gas Sorption within a Dynamic Metal-Organic Framework

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/Selective_Gas_Sorption_within_a_Dynamic_Metal_Organic_Framework/2980957
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A microporous metal-organic framework 1 Co(NDC)(4,4‘-Bipy)0.5·Gx (NDC = 2,6-naphthalenedicarboxylate; 4,4‘-Bipy = 4,4‘-bipyridine; G = guest molecules) was synthesized and structurally characterized of a doubly interpenetrated primitive cubic net. To make use of the framework flexibility, 1 was activated at temperatures of 150 and 200 °C to form 1a and 1b, respectively, exhibiting highly selective sorption behaviors of hydrogen over nitrogen-gas molecules.
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2016-06-03
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