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Facile, Thermoreversible Cycloaddition of Small Molecules to a Ruthenium(II) Arene β-Diketiminate

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https://figshare.com/articles/dataset/Facile_Thermoreversible_Cycloaddition_of_Small_Molecules_to_a_Ruthenium_II_Arene_-Diketiminate/12065763
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Formation of a vacant coordination site on a Ru center permits an unusual binding of small molecules such as ethylene, acetylene, and dihydrogen, resulting in the transformation of the chelating β-diketiminate ligand to a β-diimine. These representative species are observed during the catalytic hydrogenation of styrene.
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2007-02-26
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