Studies on a Urea-Directed Stork−Crabtree Hydrogenation. Synthesis of the C1−C9 Subunit of (+)-Zincophorin
收藏NIAID Data Ecosystem2026-03-06 收录
下载链接：
https://figshare.com/articles/dataset/Studies_on_a_Urea_Directed_Stork_Crabtree_Hydrogenation_Synthesis_of_the_C1_C9_Subunit_of_Zincophorin/2970166
下载链接
链接失效反馈官方服务：
资源简介：
A detailed account on the stereoselective synthesis of the C1−C9 subunit of (+)-zincophorin is described here. This approach features the first application of a stereoselective inverse electron demand
hetero-[4 + 2] cycloaddition of chiral allenamides in natural product synthesis. The C1−C9 subunit
matches Cossy's intermediate, thereby constituting a formal total synthesis. In addition, details of an
unusual urea-directed Stork−Crabtree hydrogenation observed during these efforts are also disclosed
here.
创建时间：
2016-06-03
