Synthesis and Isomerization of N‑Fused Tetraphenylporphyrin Ruthenium(II) Complexes
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https://figshare.com/articles/dataset/Synthesis_and_Isomerization_of_N_Fused_Tetraphenylporphyrin_Ruthenium_II_Complexes/2385643
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资源简介：
Three possible isomers of N-fused
tetraphenylporphyrin ruthenium complexes, Ru(NFTPp)Cl(CO)2 (2a–c), were isolated and fully
characterized by NMR, IR, CV, UV–vis-NIR absorption, and X-ray
crystallographic analyses. Each isomer was stable at ambient conditions
and isomerization among 2a–c occurred
at elevated temperature both in solution and in a solid state, through
the intramolecular rotational pathways. Electronic structures of 2a–c were analyzed in detail by DFT study
to reveal appreciable differences in the interaction between the NFTPp
ligand and the Ru–Cl moiety.
创建时间：
2016-02-19
