Two Isostructural 3D Lanthanide Coordination Networks (Ln = Gd3+, Dy3+) with Squashed Cuboid-Type Nanoscopic Cages Showing Significant Cryogenic Magnetic Refrigeration and Slow Magnetic Relaxation
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Two isostructural lanthanide-based 3D coordination networks [Ln = Gd3+ (1), Dy3+(2)] with densely packed distorted cuboid nanoscopic cages are reported for the first time. Magnetic characterization reveals that complex 1 shows a significant cryogenic magnetocaloric effect (−ΔSm = 44 J kg–1 K–1), whereas 2 shows slow relaxation of magnetization.
创建时间：
2016-02-17
