A New Insight into Palladium-Catalyzed Reaction of 2-Alkynylphenol with Carbon Monoxide
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https://figshare.com/articles/dataset/A_New_Insight_into_Palladium_Catalyzed_Reaction_of_2_Alkynylphenol_with_Carbon_Monoxide/2590003
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资源简介:
A novel and efficient pathway for the generation of 3-(benzofuran-3-ylmethylene)benzofuran-2(3H)-ones via a palladium-catalyzed carbonylative reaction of 2-alkynylphenol with carbon monoxide is described. The reaction proceeds through a double insertion of triple bonds during the reaction process. The products are obtained in good yields with high selectivity. A one-pot synthesis starting from 2-iodophenol and alkyne is presented as well.
创建时间:
2016-02-22



