First Magnetostructural Study on a Heterodinuclear 2,2′-Bipyrimidine-Bridged Complex
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The use of the [ReCl4(bpym)] precursor as a ligand toward the fully solvated nickel(II) metal ion affords the first example of a 2,2′-bipyrimidine-bridged ReIV–NiII complex, [ReCl4(μ-bpym)NiBr2(H2O)2] (1), whose intramolecular ferromagnetic coupling has been substantiated from both experimental and theoretical studies.
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2016-02-22



