Palladium(II)-Catalyzed Stereospecific Alkenyl C–H Bond Alkylation of Allylamines with Alkyl Iodides
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https://figshare.com/articles/dataset/Palladium_II_-Catalyzed_Stereospecific_Alkenyl_C_H_Bond_Alkylation_of_Allylamines_with_Alkyl_Iodides/7990949
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A palladium-catalyzed stereospecific alkylation of allylamines with primary and secondary alkyl iodides is described. Isoquinoline-1-carboxamide (IQA) acts as directing group to generate multisubstituted olefin products in cis configuration in moderate to good yields. Mechanistic studies suggest that alkenyl C–H bond activation is the rate-determining step.
创建时间：
2019-04-12
