Mild Reduction Route to a Redox-Active Silicon Complex: Structure and Properties of (IP2–)2Si and (IP–)2Mg(THF) (IP = α-Iminopyridine)
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https://figshare.com/articles/dataset/Mild_Reduction_Route_to_a_Redox_Active_Silicon_Complex_Structure_and_Properties_of_IP_sup_2_sup_sub_2_sub_Si_and_IP_sup_sup_sub_2_sub_Mg_THF_IP_Iminopyridine_/2523145
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Use of SiCl4 as an organometallic reagent can be complicated by access to Si3+, Si2+, and unwanted sigmatropic rearrangements. Herein we report a mild reduction route, using (IP–)2Mg(THF) (1) and Mg metal, to cleanly access (IP2–)2Si (2). Electrochemical measurements show that IP2– is stabilized by Si4+ > Al3+ > Mg2+.
创建时间：
2016-02-20
