Consecutive Gold(I)-Catalyzed Cyclization Reactions of o‑(Buta-1,3-diyn-1-yl-)-Substituted N‑Aryl Ureas: A One-Pot Synthesis of Pyrimido[1,6‑a]indol-1(2H)‑ones and Related Systems
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https://figshare.com/articles/dataset/Consecutive_Gold_I_Catalyzed_Cyclization_Reactions_of_i_o_i_Buta_1_3_diyn_1_yl_Substituted_i_N_i_Aryl_Ureas_A_One_Pot_Synthesis_of_Pyrimido_1_6_i_a_i_indol_1_2_i_H_i_ones_and_Related_Systems/2408089
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Treatment of readily available o-(buta-1,3-diyn-1-yl-)-substituted N-aryl ureas such as 1 with the Au(I)-catalyst 11 affords, via a twofold cyclization process, the isomeric pyrimido[1,6-a]indol-1(2H)-one 3 in good yield.
创建时间:
2016-02-19



