Laccase-catalyzed iodination of different mono-methoxy-substituted phenolic compounds (structures: see Figure 2).
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aReaction conditions: 4 mM educt, 50 mM potassium iodide, 100 µM ABTS and 0.25 mg mL−1T. versicolor laccase, % conversion was calculated as the relative decrease in educt peak area compared to enzyme-free control reactions.bReaction batches were extracted with ethyl acetate and educts and products were analyzed by HPLC-UV/MS, molecular mass of iodide atom: 126.9 g mol−1, for molecular masses of educts see Figure 2.cRelative peak area of products, average values and standard deviations of n = 3 replicate experiments.
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2015-12-02
