γ,δ,ε-C(sp3)–H Functionalization through Directed Radical H‑Abstraction
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https://figshare.com/articles/dataset/__C_sp_sup_3_sup_H_Functionalization_through_Directed_Radical_H_Abstraction/2207491
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资源简介：
Aliphatic amides are selectively functionalized at the γ- and δ-positions through directed radical 1,5 and 1,6 H-abstractions, respectively. The initially formed γ- or δ-lactams are intercepted by N-iodosuccinimide and trimethylsilyl azide, leading to double and triple C–H functionalizations at the γ-, δ-, and ε-positions. This new reactivity is exploited to convert alkyls into amino alcohols and allylic amines.
创建时间：
2016-02-15
