Single Step Synthesis of Acetylene-Substituted Oxacalix[4]arenes
收藏NIAID Data Ecosystem2026-03-08 收录
下载链接：
https://figshare.com/articles/dataset/Single_Step_Synthesis_of_Acetylene_Substituted_Oxacalix_4_arenes/2285602
下载链接
链接失效反馈官方服务：
资源简介：
Oxacalixarenes
bearing acetylene groups are synthesized in a single
step by nucleophilic aromatic substitution reactions of orcinol with
various 1,5-diethynyl-2,4-difluorobenzenes. Thermodynamic equilibration
of the cyclooligomer mixtures was accomplished for arylethynyl activating
groups, leading to increased yields of the corresponding oxacalix[4]arenes.
A 1,3-alternate macrocycle conformation is observed in the solid state,
presenting a large V-shaped π-surface.
创建时间：
2016-02-17
