Multicomponent Synthesis of Pyran-2-ylidene Chromium(0) and Tungsten(0) Fischer Carbene Complexes
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https://figshare.com/articles/dataset/Multicomponent_Synthesis_of_Pyran_2_ylidene_Chromium_0_and_Tungsten_0_Fischer_Carbene_Complexes/2778043
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资源简介:
A new reaction between chromium(0) and tungsten(0) carbene complexes 1 and alkynyl esters or ketones 2 in the presence of NMO to yield pyran-2-ylidene complexes 3 has been explored. Here, we discuss the scope of the reaction and propose a plausible mechanistic pathway. The method is a new multicomponent approach for the synthesis of pyranylidene carbene complexes.
创建时间:
2010-04-12



