A Non-Heme Iron(III) Complex with Porphyrin-like Properties That Catalyzes Asymmetric Epoxidation
收藏Figshare2016-02-20 更新2026-04-29 收录
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https://figshare.com/articles/dataset/A_Non_Heme_Iron_III_Complex_with_Porphyrin_like_Properties_That_Catalyzes_Asymmetric_Epoxidation/2494009
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资源简介：
In this report, we describe an iron(III) complex containing a carbazole-based tridentate ligand that catalyzes highly enantioselective asymmetric epoxidation of (E)-alkenes at room temperature. The non-heme iron(III) complex has a five-coordinated trigonal-bipyramidal structure, and its two-electron oxidized state has the similar electronic structure as that of iron porphyrins.
创建时间：
2016-02-20
