Anionic Multisubstituted 1,2-Azaborolyl Ligands: Syntheses, Characterization, and Coordination Chemistry
收藏NIAID Data Ecosystem2026-03-06 收录
下载链接：
https://figshare.com/articles/dataset/Anionic_Multisubstituted_1_2_Azaborolyl_Ligands_Syntheses_Characterization_and_Coordination_Chemistry/2934817
下载链接
链接失效反馈官方服务：
资源简介：
Two synthetic methods for the preparation of tri- or tetrasubstituted 1,2-azaborolyls (Ab) are described. Both tri- and tetrasubstituted Ab rings can be conveniently attained via either dilithiation-directed or Cp2ZrII-mediated cyclization followed by transmetalation in good yields. In particular, anionic 1,2,4-trimethyl-1,2-azaborolyl and 1,2,3,4-tetramethyl-1,2-azaborolyl, readily prepared through our methods, have been demonstrated as good supporting ancillary ligands in group IV metal complexes.
创建时间：
2016-02-27
